Functionalized vinylsilanes via highly efficient and recyclable Pt-nanoparticle catalysed hydrosilylation of alkynes.
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DOI: 10.1039/c7dt00544j
Abstract: A mild, selective and facile synthesis of vinylsilanes via a recyclable platinum nanoparticle catalysed hydrosilylation of alkynes is reported. Various functionalized alkynes are selectively hydrosilylated to furnish functional β-E vinylsilanes in high yields. The catalytic… read more here.
Keywords: hydrosilylation alkynes; catalysed hydrosilylation; vinylsilanes via; nanoparticle catalysed ... See more keywords
Gold nanoparticle-catalysed functionalization of carbon-hydrogen bonds by carbene transfer reactions.
Sign Up to like & getrecommendations! Published in 2022 at "Dalton transactions"
DOI: 10.1039/d1dt04351j
Abstract: Gold nanoparticles stabilized by NHC ligands and supported onto reduced graphene oxide (rGO) catalyse the functionalization of cyclohexane and benzene C-H bonds upon insertion of carbene CHCO2Et (from N2CHCO2Et) groups. This is the first example… read more here.
Keywords: catalysed functionalization; functionalization; carbon hydrogen; functionalization carbon ... See more keywords