A naphthalene-fused dimer of an anti-aromatic expanded isophlorin.
Sign Up to like & getrecommendations! Published in 2017 at "Chemical communications"
DOI: 10.1039/c7cc04050d
Abstract: We report the first synthesis of a covalent expanded isophlorin dimer from two 24-π doubly S-confused sapphyrin-like pentathiaisophlorins. It exhibits marginal peripheral aromaticity rather than strong global diatropicity or paratropicity and weak intermacrocycle electronic communication.… read more here.
Keywords: dimer anti; anti aromatic; naphthalene fused; expanded isophlorin ... See more keywords
Cycloaddition of Benzyne to Naphthalene-fused Tetracene with a Twisted pi-Surface
Sign Up to like & getrecommendations! Published in 2017 at "Chemistry Letters"
DOI: 10.1246/cl.161170
Abstract: The functionalization of polycyclic aromatic hydrocarbons (PAHs) with arynes has received substantial attention because it offers a way to create π-extended PAHs as well as compounds containing rigid 3D structures. Herein, we report cycloadditions of… read more here.
Keywords: twisted surface; cycloaddition benzyne; tetracene twisted; naphthalene fused ... See more keywords