Stabilizing the Naphthalenediimide Radical within a Tetracationic Cyclophane.
Sign Up to like & getrecommendations! Published in 2019 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.9b08926
Abstract: Organic radicals are of importance in developing smart materials that have paramagnetic and/or near-infrared optical properties. Their practical applications, however, are limited by the labile nature of the radicals. Here, we demonstrate that by using… read more here.
Keywords: tetracationic cyclophane; radical within; stabilizing naphthalenediimide; cyclophane ... See more keywords
A supramolecular naphthalenediimide radical anion through host-guest interactions for photooxidation of alkylarenes to carbonyls.
Sign Up to like & getrecommendations! Published in 2024 at "Chemical communications"
DOI: 10.1039/d4cc02374a
Abstract: A supramolecular naphthalenediimide radical anion was developed through host-guest interactions between NDI and cucurbit[7]uril (CB[7]), which can be greatly promoted in the presence of chloride ions to obtain Cl˙ and NDI-2CB[7]˙-. Under the synergistic action… read more here.
Keywords: guest interactions; supramolecular naphthalenediimide; radical anion; host guest ... See more keywords