Photochemical Oxidative Coupling of 2‐Naphthols using a Hybrid Reduced Graphene Oxide/Manganese Dioxide Nanocomposite under Visible‐Light Irradiation
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DOI: 10.1002/cctc.201701470
Abstract: We describe a simple, cost‐effective, efficient, and high‐yielding photocatalytic approach for the oxidative self‐dimerization of 2‐naphthols using a semiconductor–metal hybrid that consists of intercalated manganese dioxide nanoparticles in reduced graphene oxide (rGO/MnO2) under visible‐light irradiation.… read more here.
Keywords: graphene oxide; naphthols using; visible light; reduced graphene ... See more keywords
Dearomatization of naphthols using oxy-allyl cations: efficient construction of α-all-carbon quaternary center-containing 2-(2-oxocycloalkyl)cycloalkyl diketones
Sign Up to like & getrecommendations! Published in 2018 at "Organic chemistry frontiers"
DOI: 10.1039/c8qo00783g
Abstract: A novel strategy for the dearomatization of naphthols using in situ generated oxy-allyl cations is reported. Both α- and β-naphthols can work well in this process. Using this catalyst-free methodology, various structurally diverse α-quaternary center-containing… read more here.
Keywords: dearomatization naphthols; naphthols using; allyl cations; oxy allyl ... See more keywords