Noble-Metal Substitution in Hemoproteins: An Emerging Strategy for Abiological Catalysis.
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DOI: 10.1021/acs.accounts.8b00586
Abstract: Enzymes have evolved to catalyze a range of biochemical transformations with high efficiencies and unparalleled selectivities, including stereoselectivities, regioselectivities, chemoselectivities, and substrate selectivities, while typically operating under mild aqueous conditions. These properties have motivated extensive… read more here.
Keywords: strategy; reactivity; native enzymes; metal substitution ... See more keywords