Formation of [(CO)(HCCH)Tp'W=NCH(CH3)CH(CH3)N=WTp'(HCCH)(CO)][I3]2 by oxidation of Tp'W(CO)(HCCH)(NCHCH3) and radical dimerization
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DOI: 10.1016/j.jorganchem.2017.02.032
Abstract: Abstract By treating Tp'W(CO)(HCCH)(NCHCH3) with iodine, a 1 e− oxidation of the metal complex occurs leading to radical coupling through the β-carbons of two 1-azavinylidene ligands. Formation of the diimido bridged dimer [(Tp'W(CO)(HCCH))2(μ-NCH(CH3)CH(CH3)N)][I3]2 occurs diastereoselectively;… read more here.
Keywords: oxidation; nch ch3; ch3; hcch nch ... See more keywords