Near thermal, selective liberation of hydrogen from formic acid catalysed by copper hydride ate complexes.
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DOI: 10.1039/d2dt03764e
Abstract: A near thermal two-step catalytic cycle for the selective release of hydrogen from formic acid by mononuclear cuprate anions was revealed using multistage mass spectrometry experiments, deuterium labelling and DFT calculations. In gas-phase ion-molecule reactions,… read more here.
Keywords: formic acid; copper hydride; copper; near thermal ... See more keywords
Heat transport via a local two-state system near thermal equilibrium
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DOI: 10.1088/1367-2630/aadf09
Abstract: Heat transport in spin-boson systems near the thermal equilibrium is systematically investigated. An asymptotically exact expression for the thermal conductance in a low-temperature regime wherein transport is described via a co-tunneling mechanism is derived. This… read more here.
Keywords: heat transport; near thermal; transport; thermal equilibrium ... See more keywords