ROPs of l-lactide catalyzed by neat Tin(II)2-ethylhexanoate - Influence of the reaction conditions on Tm and ΔHm
Sign Up to like & getrecommendations! Published in 2021 at "Polymer"
DOI: 10.1016/j.polymer.2021.124122
Abstract: Abstract l -Lactide was polymerized by means of neat SnOct2 with variation of LA/Cat ratio, temperature and time. The resulting cyclic polylactides crystallized spontaneously at 160 °C or below, but needed nucleation via mechanical stress at… read more here.
Keywords: lactide catalyzed; ethylhexanoate influence; tin ethylhexanoate; neat tin ... See more keywords
High molar mass cyclic poly(l-lactide) obtained by means of neat tin(ii) 2-ethylhexanoate
Sign Up to like & getrecommendations! Published in 2020 at "Polymer Chemistry"
DOI: 10.1039/d0py00811g
Abstract: L-Lactide was polymerized in bulk at 120, 140, 160 and 180 °C with neat tin(II) 2-ethylhexanoate (SnOct2) as the catalyst. At 180 °C the Lac/Cat ratio was varied from 25/1 up to 8000/1 and at… read more here.
Keywords: tin ethylhexanoate; mass; tin; lac cat ... See more keywords