Guest-Induced Switchable Breathing Behavior in a Flexible Metal-Organic Framework with Pronounced Negative Gas Pressure.
Sign Up to like & getrecommendations! Published in 2018 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.8b01408
Abstract: Flexible metal-organic frameworks (MOFs) have attracted great interest for their dynamically structural transformability in response to external stimuli. Herein, we report a switchable "breathing" or "gate-opening" behavior associated with the phase transformation between a narrow… read more here.
Keywords: flexible metal; pronounced negative; switchable breathing; metal organic ... See more keywords
The role of temperature and adsorbate on negative gas adsorption transitions of the mesoporous metal-organic framework DUT-49.
Sign Up to like & getrecommendations! Published in 2020 at "Faraday discussions"
DOI: 10.1039/d0fd00013b
Abstract: Unusual adsorption phenomena, such as breathing and negative gas adsorption (NGA), are rare and challenge our thermodynamic understanding of adsorption in deformable porous solids. In particular, NGA appears to break the rules of thermodynamics in… read more here.
Keywords: adsorption; role temperature; temperature; negative gas ... See more keywords
Engineering micromechanics of soft porous crystals for negative gas adsorption†
Sign Up to like & getrecommendations! Published in 2020 at "Chemical Science"
DOI: 10.1039/d0sc03727c
Abstract: Framework materials at the molecular level, such as metal–organic frameworks (MOF), were recently found to exhibit exotic and counterintuitive micromechanical properties. Stimulated by host–guest interactions, these so-called soft porous crystals can display counterintuitive adsorption phenomena… read more here.
Keywords: adsorption; building blocks; gas adsorption; negative gas ... See more keywords