Negative Photochromic 3-Phenylperylenyl-Bridged Imidazole Dimer Offering Quantitative and Selective Bidirectional Photoisomerization with Visible and Near-Infrared Light.
Sign Up to like & getrecommendations! Published in 2023 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.2c13331
Abstract: Selective bidirectional photoisomerization reactions with high conversion ratios between stable and metastable isomers by irradiation of photochromic molecules with visible light of different wavelengths have been an important issue for many years. For negative photochromic… read more here.
Keywords: selective bidirectional; bidirectional photoisomerization; imidazole dimer; negative photochromic ... See more keywords
Acceleration of the thermal back-reaction and the finding of a non-photochromic isomer for a negative photochromic binaphthyl-bridged imidazole dimer.
Sign Up to like & getrecommendations! Published in 2023 at "Chemical communications"
DOI: 10.1039/d2cc06942c
Abstract: The development of visible or near-infrared (NIR) light-responsive fast photoswitchable molecules for the real-time, non-contact control of physical and chemical properties has received increased attention because of the non-invasive features to materials and biological tissues.… read more here.
Keywords: back reaction; photochromic binaphthyl; binaphthyl bridged; thermal back ... See more keywords