Synthesis of Trimethyltriazacyclohexane (Me3tach) Sandwich Complexes of Uranium, Neptunium, and Plutonium Triiodides: (Me3tach)2AnI3.
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DOI: 10.1021/acs.inorgchem.2c03306
Abstract: 1,3,5-Trimethyl-1,3,5-triazacyclohexane (Me3tach) readily complexes uranium triiodide to form (Me3tach)2UI3. The complex is soluble in THF and arenes and can function as a source of UI3 to form organometallic U(III) complexes. When dissolved in pyridine (py),… read more here.
Keywords: complexes uranium; thf; me3tach; neptunium plutonium ... See more keywords
Theoretical insights into the possible applications of amidoxime-based adsorbents in neptunium and plutonium separation.
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DOI: 10.1039/d1dt01900g
Abstract: Efficient separation of neptunium and plutonium from spent nuclear fuel is essential for advanced nuclear fuel cycles. At present, the development of effective actinide separation ligands has become a top priority. As common adsorbents for… read more here.
Keywords: separation; based adsorbents; amidoxime based; neptunium plutonium ... See more keywords
Isostructural σ-hydrocarbyl phospholide complexes of uranium, neptunium, and plutonium.
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DOI: 10.1039/d2cc04803e
Abstract: σ-Hydrocarbyl complexes of the form [M(η5-PC4Me4)2(μ-η1:η6-CH2Ph)2K(η6-arene)] (M = La, Ce, Pr, U, Np, Pu; arene = benzene or toluene) were synthesised in one-pot reactions from [MI3(THF)4], or [U(BH4)3(toluene)] (M = U). All complexes were examined… read more here.
Keywords: complexes uranium; isostructural hydrocarbyl; neptunium plutonium; hydrocarbyl phospholide ... See more keywords