Catalytic Net Oxidative C-C Activation and Silylation of Cyclopropanols with a Traceless Acetal Directing Group.
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DOI: 10.1021/acscatal.1c04628
Abstract: Redox-neutral carbon-carbon (C-C) bond activation and functionalization strategies of cyclopropanols that give metallo homoenolate have offered merits to construct a range of useful β-functionalized ketones in an inverse-polarity fashion. Discovery and identification of oxidative C-C… read more here.
Keywords: net oxidative; silylation; oxidative activation; acetal directing ... See more keywords