Versatile Coordination Modes of Multidentate Neutral Amine Ligands with Group 1 Metal Cations
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DOI: 10.1021/acs.inorgchem.1c03786
Abstract: This work comprehensively investigated the coordination chemistry of a hexa-dentate neutral amine ligand, namely, N,N′,N”-tris-(2-N-diethylaminoethyl)-1,4,7-triaza-cyclononane (DETAN), with group-1 metal cations (Li+, Na+, K+, Rb+, Cs+). Versatile coordination modes were observed, from four-coordinate trigonal pyramidal to… read more here.
Keywords: neutral amine; coordination modes; coordination; chemistry ... See more keywords