Two Synthetic Approaches to Coinage Metal(I) Mesocates: Electrochemical versus Chemical Synthesis
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DOI: 10.1021/acs.inorgchem.2c02243
Abstract: We report two different approaches to isolate neutral and cationic mesocate-type metallosupramolecular architectures derived from coinage monovalent ions. For this purpose, we use a thiocarbohydrazone ligand, H2L (1), conveniently tuned with bulky phosphine groups to… read more here.
Keywords: two synthetic; h2l; synthetic approaches; approaches coinage ... See more keywords
Expedient Syntheses of Neutral and Cationic Au(I)–NHC Complexes
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DOI: 10.1021/acs.organomet.7b00622
Abstract: The synthesis and isolation of gold(I) precatalysts often requires the generation of several isolable intermediates as well as numerous purification steps. New protocols for the expedient synthesis of neutral [Au(OH)(NHC)] and [Au(CH2COCH3)(NHC)] species from [AuCl(NHC)]… read more here.
Keywords: cationic nhc; nhc; nhc complexes; expedient syntheses ... See more keywords
Orbital control over the metal vs. ligand reduction in a series of neutral and cationic bis(cyclopentadienyl) Ti(IV) complexes
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DOI: 10.1039/c7nj03746e
Abstract: Quantum chemistry calculations showed that the first reduction, as experimentally observed by cyclic voltammetry for a series of neutral and cationic functionalised bis(cyclopentadienyl) titanium(IV) derivatives, is metal based, involving the chemically and electrochemically reversible TiIV/TiIII… read more here.
Keywords: reduction; bis cyclopentadienyl; chemistry; neutral cationic ... See more keywords