Neutral dinuclear gold(I) complexes with N-phosphanyl, N-heterocyclic carbenes (NHCPs)
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DOI: 10.1016/j.jorganchem.2016.09.030
Abstract: Abstract Neutral dinuclear gold(I) complexes having general formula [Au 2 Cl 2 (NHCP)] (NHCP = N -phosphanyl N -heterocyclic carbene) have been synthesized by two different synthetic procedures: i) transmetalation of the NHCP ligand from the… read more here.
Keywords: neutral dinuclear; phosphanyl heterocyclic; gold; dinuclear gold ... See more keywords
Neutral Dinuclear Copper(I)-NHC Complexes: Synthesis and Application in the Hydrosilylation of Ketones
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DOI: 10.1021/acscatal.6b02723
Abstract: The synthesis of a class of highly stable neutral dinuclear Cu(I)-NHC complexes using 1,2,4-triazole as a bridging ligand is described. Various NHCs were used to generate a library of [Cu(μ-trz)(NHC)]2 complexes. Interestingly, [Cu(μ-trz)(IPr)]2 was found… read more here.
Keywords: nhc; neutral dinuclear; hydrosilylation ketones; nhc complexes ... See more keywords