Redox Neutral Radical-Relay Cobalt Catalysis toward C-H Fluorination and Amination.
Sign Up to like & getrecommendations! Published in 2020 at "Organic letters"
DOI: 10.1021/acs.orglett.0c01072
Abstract: A redox neutral radical-relay cobalt-catalyzed intramolecular C-H fluorination of N-fluoroamides featuring the in situ formed cobalt fluorides as the latent radical fluorinating agents is reported. Moreover, the reactivity of such a cobalt catalysis could be… read more here.
Keywords: cobalt; fluorination; redox neutral; neutral radical ... See more keywords
Neutral, π-Radical-Conjugated Microporous Polymer Films of Nanoscale Thickness for Potential Use in Magnetoelectronics and Sensor Devices
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DOI: 10.1021/acsanm.9b00776
Abstract: π-Radical conjugated microporous polymers (CMPs) are highly appealing for optoelectronics, especially optical response-based sensor devices, and their thin film fabrication is demanding for develop... read more here.
Keywords: neutral radical; conjugated microporous; radical conjugated; microporous polymer ... See more keywords
CAS Calculation of the Excited States of the Methylthio Neutral Radical and Its Ions
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DOI: 10.1021/acsomega.0c01883
Abstract: The complete active space (CASSCF) and the multiconfiguration second-order perturbation theory (CASPT2) calculations with 6-311++G(3df,3pd) gauss basis sets are performed for several electronic states of the methylthio neutral radical and its cation and anion. Twenty-two… read more here.
Keywords: states methylthio; excited states; methylthio neutral; cas calculation ... See more keywords