Redox-Neutral Synthesis of Sulfilimines through the S-Alkylation of Sulfenamides.
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DOI: 10.1021/acs.orglett.3c01060
Abstract: In this work, we developed a metal-free and redox-neutral strategy for the selective S-alkylation of sulfenamides under basic conditions to yield sulfilimines. The key step involves the resonance between bivalent nitrogen-centered anions, generated after deprotonation… read more here.
Keywords: neutral synthesis; synthesis sulfilimines; alkylation sulfenamides; alkylation ... See more keywords