Redox-Neutral Transformations of Carbon Dioxide Using Coordinatively Unsaturated Late Metal Silyl Amide Complexes.
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DOI: 10.1021/acs.inorgchem.2c03453
Abstract: Two-coordinate silylamido complexes of nickel and copper rapidly react with CO2 to selectively form a new cyanate ligand along with hexamethyldisiloxane byproducts. Mechanistic insight into these reactions was obtained from the synthesis of proposed intermediates,… read more here.
Keywords: carbon dioxide; dioxide using; neutral transformations; redox neutral ... See more keywords