Exploring Molecular Complexity by N-Heterocyclic Carbene Organocatalysis: New Activation and Reaction Diversity.
Sign Up to like & getrecommendations! Published in 2022 at "Chemical record"
DOI: 10.1002/tcr.202200219
Abstract: The development of catalytic synthetic approaches towards molecular complexity from simple materials continues to be an ultimate goal in synthetic chemistry. Over the past decades, N-heterocyclic carbene (NHC) organocatalysis has been extensively investigated to provide… read more here.
Keywords: new activation; molecular complexity; organocatalysis; complexity ... See more keywords
New activation mechanism for half-sandwich organometallic anticancer complexes† †Electronic supplementary information (ESI) available. CCDC 1420046–1420052 and 1569283. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c7sc05058e
Sign Up to like & getrecommendations! Published in 2018 at "Chemical Science"
DOI: 10.1039/c7sc05058e
Abstract: Half-sandwich RhIII anticancer complexes with activated Cp* rings not only undergo sequential CH3 H–D exchange, but also react with biological dienes, generating RhI Diels–Alder adducts in aqueous media at ambient temperature. read more here.
Keywords: activation mechanism; half sandwich; anticancer complexes; new activation ... See more keywords