One-step synthesis of new aluminum hydrides bearing a highly sterically hindered acenaphthene-1,2-diimine ligand
Sign Up to like & getrecommendations! Published in 2020 at "Mendeleev Communications"
DOI: 10.1016/j.mencom.2020.01.031
Abstract: Treatment of a bulky dbhmp-bian ligand (dbhmp-bian = = 1,2-bis[(2,6-dibenzhydryl-4-methylphenyl)imino]acenaphthene) by 1 equiv. of LiAlH4 or mixture of 3/4 equiv. LiAlH4 and 1/3 eqiuv. AlCl3 in tetrahydrofuran results in new hydrides [(dbhmp-bian)AlH2(THF)]-[Li(THF)4]+ and (dbhmp-bian)AlH(THF), respectively. Both complexes were… read more here.
Keywords: dbhmp bian; new aluminum; synthesis new; step synthesis ... See more keywords
New Aluminum Syntactic Foam: Synthesis and Mechanical Characterization
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DOI: 10.3390/ma15155320
Abstract: Metal matrix syntactic foams (MMSF) are advanced cellular materials constituted by a system of a minimum of two phases, in which a dispersion of hollow particles is embedded by a continuous metal matrix. The incorporation… read more here.
Keywords: synthesis mechanical; aluminum; aluminum syntactic; foam synthesis ... See more keywords