New chiral stationary phases for liquid chromatography based on small molecules: Development, enantioresolution evaluation and chiral recognition mechanisms.
Sign Up to like & getrecommendations! Published in 2019 at "Chirality"
DOI: 10.1002/chir.23142
Abstract: Recently, we reported the development of new chiral stationary phases (CSPs) for liquid chromatography (LC) based on chiral derivatives of xanthones (CDXs). Based on the most promising CDX selectors, 12 new CSPs were successfully prepared… read more here.
Keywords: small molecules; chromatography based; chiral stationary; liquid chromatography ... See more keywords
A new chiral stationary phase based on noscapine: Synthesis, enantioseparation, and docking study.
Sign Up to like & getrecommendations! Published in 2022 at "Chirality"
DOI: 10.1002/chir.23488
Abstract: Noscapine is an isolated compound from the opium poppy, with distinctive chiral structure and chemistry, interacts with other compounds due to having multiple π-acceptors, hydrogen bond acceptors, and ionic sites. Therefore, it has promising applicability… read more here.
Keywords: stationary phase; new chiral; phase based; phase ... See more keywords
Synthesis of new chiral mono- and diacrylates for ferro- and antiferroelectric liquid crystals
Sign Up to like & getrecommendations! Published in 2018 at "Journal of Molecular Liquids"
DOI: 10.1016/j.molliq.2018.09.017
Abstract: Abstract The synthesis and characterization of new, chiral and reactive single liquid crystals based on biphenyl benzoate core are described. Compounds are terminated with partially perfluorinated alkoxy chain (monoacrylates) or acryloyloxy-alkoxy chain (diacrylates) on the… read more here.
Keywords: mono diacrylates; synthesis new; liquid; liquid crystals ... See more keywords
New chiral ECD-Raman spectroscopy of atropisomeric naphthalenediimides.
Sign Up to like & getrecommendations! Published in 2022 at "Chemical communications"
DOI: 10.1039/d1cc06974h
Abstract: In this study, we found that a recently discovered ECD-Raman effect dominated over the natural Raman optical activity in a series of atropisomeric naphthalenediimides, and we investigated the kind of information about the molecular structure… read more here.
Keywords: atropisomeric naphthalenediimides; chiral ecd; spectroscopy; ecd raman ... See more keywords
A new chiral rare-earth organic framework constructed by tartaric acid: synthesis, structural, thermal investigations and optical properties.
Sign Up to like & getrecommendations! Published in 2022 at "Acta crystallographica. Section C, Structural chemistry"
DOI: 10.1107/s2053229622004302
Abstract: Hydrothermal reactions of rare-earth cerium with L-tartaric acid afford a new coordination polymer, namely, poly[[triaqua(μ4-L-tartrato)cerium(III)] chloride], {[Ce(C4H4O6)(H2O)3]Cl}n, (1). The structure was determined by single-crystal X-ray diffraction analysis and further characterized by IR and UV-Vis spectroscopy,… read more here.
Keywords: chiral rare; tartaric acid; ray diffraction; new chiral ... See more keywords
Synthesis and crystal structures of new chiral 3-amino-2H-azirines and the Pd complex of one of them
Sign Up to like & getrecommendations! Published in 2023 at "Acta Crystallographica. Section C, Structural Chemistry"
DOI: 10.1107/s2053229623001468
Abstract: Three new 3-amino-2H-azirine derivatives have been synthesized as racemates or mixtures of diastereoisomers. Comparison of their crystal structures with those of the 11 other 3-amino-2H-azirines in the literature reveal that the formal N—C single bond… read more here.
Keywords: synthesis crystal; new chiral; structures new; crystal structures ... See more keywords
A new chiral phenomenon of orientational chirality, its synthetic control and computational study
Sign Up to like & getrecommendations! Published in 2023 at "Frontiers in Chemistry"
DOI: 10.3389/fchem.2022.1110240
Abstract: A new type of chirality, orientational chirality, consisting of a tetrahedron center and a remotely anchored blocker, has been discovered. The key structural element of this chirality is characterized by multiple orientations directed by a… read more here.
Keywords: phenomenon; computational study; new chiral; orientational chirality ... See more keywords
Biological Properties of New Chiral 2-Methyl-5,6,7,8-tetrahydroquinolin-8-amine-based Compounds
Sign Up to like & getrecommendations! Published in 2020 at "Molecules"
DOI: 10.3390/molecules25235561
Abstract: The synthesis of a small library of 8-substituted 2-methyl-5,6,7,8-tetrahydroquinoline derivatives is presented. All the compounds were tested for their antiproliferative activity in non-cancer human dermal microvascular endothelial cells (HMEC-1) and cancer cells: human T-lymphocyte cells… read more here.
Keywords: chiral methyl; methyl tetrahydroquinolin; tetrahydroquinolin amine; biological properties ... See more keywords