A new metal–organic framework based on 4,4′-bibenzoic acid-2,2′-sulfone: synthesis, crystal structure and magnetic property
Sign Up to like & getrecommendations! Published in 2020 at "Journal of Porous Materials"
DOI: 10.1007/s10934-020-01002-y
Abstract: A new metal–organic framework (MOF), namely, {[Ni(BPS)(4,4′-bipy)]n}, (BPS = 4,4′-bibenzoic acid-2,2′-sulfone, bipy = 4,4-Bipyridine) (1), with 3D framework has been synthesized under solvothermal condition and characterized by single crystal X-ray diffraction, PXRD, TGA, FT-IR and SQUID magnetometry. Topological analysis… read more here.
Keywords: acid sulfone; framework; metal organic; new metal ... See more keywords
Three New Metal Complexes with Imidazole-Containing Tripodal Ligands as Fluorophores for Nitroaromatics- and Ion-Selective Sensing.
Sign Up to like & getrecommendations! Published in 2020 at "Inorganica chimica acta"
DOI: 10.1016/j.ica.2019.119310
Abstract: Three new metal-organic complexes [Cd(TIPA)(suc)0.5(NO3)·1/2H2O]n (1), [Ni(TIPA)(tda)0.5(H2O)·1/4H2O]n (2) and [Cd(TIPA)(tda)0.5·11/2H2O] (3) were synthesized via rigid tripodal ligand tris(4-(1H-imidazol-1-yl)phenyl)amine (TIPA) and three dicarboxylic acids; either succinic acid (H2suc) or 2,5-thiophenedicarboxylic acid (H2tda). Crystallographic data for 1… read more here.
Keywords: tripodal; three new; new metal; metal ... See more keywords
New metal cofactors and recent metallocofactor insights.
Sign Up to like & getrecommendations! Published in 2019 at "Current opinion in structural biology"
DOI: 10.1016/j.sbi.2018.12.008
Abstract: A vast array of metal cofactors are associated with the active sites of metalloenzymes. This Opinion describes the most recently discovered metal cofactor, a nickel-pincer nucleotide (NPN) coenzyme that is covalently tethered to lactate racemase… read more here.
Keywords: metal cofactors; cofactors recent; new metal; metal ... See more keywords
Highly effective Brønsted base/lewis acid cooperative catalysis: a new Cd metal–organic framework for the synthesis of Hantzsch 1,4-DHPs at ambient temperature
Sign Up to like & getrecommendations! Published in 2017 at "New Journal of Chemistry"
DOI: 10.1039/c7nj01509g
Abstract: A new 3D metal–organic framework {[Cd3(BDC)3(OPP)(DMF)2]·2DMA}n (TMU-33) has been synthesized using a novel V-shaped imine-functionalized ligand, N,N′-(oxybis(4,1-phenylene))bis(1-(pyridin-4-yl)methanimine) (OPP), terephthalic acid (H2BDC), and Cd(NO3)2·4H2O and has been fully characterized. The function of the imine moiety of… read more here.
Keywords: framework; metal organic; new metal; ambient temperature ... See more keywords
Two new metal-chalcogenide-cluster-based frameworks with single metal ions of Zn2+(/Sb3+) serving as inter-cluster linkers.
Sign Up to like & getrecommendations! Published in 2022 at "Dalton transactions"
DOI: 10.1039/d1dt04132k
Abstract: Two new metal-chalcogenide-cluster-based frameworks, in which P1-ZnSnS clusters are linked to each other by both corner-shared S2- ions and single metal ions of Zn2+ (or Sb3+) to form one new 3D (3,4)-connected network (MCCF-22) and… read more here.
Keywords: new metal; two new; cluster; chalcogenide cluster ... See more keywords
Synthesis, Characterization, and In Vivo Anti-Cancer Activity of New Metal Complexes Derived from Isatin-N(4)antipyrinethiosemicarbazone Ligand Against Ehrlich Ascites Carcinoma Cells
Sign Up to like & getrecommendations! Published in 2019 at "Molecules"
DOI: 10.3390/molecules24183313
Abstract: The current study aimed to synthesize new metal coordination complexes with potential biomedical applications. Metal complexes were prepared via the reaction of isatin-N(4)anti- pyrinethiosemicarbazone ligand 1 with Cu(II), Ni(II), Co(II), Zn(II), and Fe(III) ions. The… read more here.
Keywords: new metal; metal; metal complexes; anti cancer ... See more keywords