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Published in 2021 at "Journal of Molecular Structure"
DOI: 10.1016/j.molstruc.2020.129012
Abstract: Abstract One 2p-3d-4f multispin complex [Cu(hfac)(4-Me-3-NITtrz)2][Tb(hfac)4]·H2O (1) has been obtained based on a functionalized nitronyl nitroxide radical 4-Me-3-Nit-trz (in which, 4-Me-3-Nit-trz = 2-[3-(4-methyl-l,2,4-triazolyl)]-4,4,5,5-tetramethylimidazoline-1-oxyl-3-oxide, hfac = hexafluoroacetylacetone). Complex 1 crystallizes in tetragonal system, I 4 ¯ space group. The central…
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Keywords:
nitronyl nitroxide;
terbium copper;
new mononuclear;
structure ... See more keywords
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Published in 2019 at "Polyhedron"
DOI: 10.1016/j.poly.2019.03.028
Abstract: Abstract Two new d10 metal coordination polymers (CPs), [Zn(L)NO3]n (1) and [Cd(L)I2]n (2) (L = 4-(3-Pyridyl)-2H-1,2,3-triazole), have been designed and synthesized from ZnII/CdII ions and the rigid L ligand. The CPs 1 and 2 have been structurally…
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Keywords:
two new;
new mononuclear;
coordination polymers;
mononuclear zinc ... See more keywords
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Published in 2018 at "Journal of Coordination Chemistry"
DOI: 10.1080/00958972.2018.1447668
Abstract: Abstract Four new mononuclear copper(II) complexes with methyl acetoacetate and benzoylacetone in the presence of 1,10-phenanthroline and 2,2′-bipyridine were synthesized and characterized by elemental analyses, FT-IR, and UV–Vis spectroscopy. The molecular structures of complexes [Cu(MAA)(bpy)(ClO4)]…
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Keywords:
copper complexes;
new mononuclear;
mononuclear copper;
structure ... See more keywords
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Published in 2021 at "Molecules"
DOI: 10.3390/molecules26082288
Abstract: Herein, we report the synthesis of eight new mononuclear and binuclear Co2+, Ni2+, Cu2+, and Zn2+ methoxy thiosemicarbazone (MTSC) complexes aiming at obtaining thiosemicarbazone complex with potent biological activity. The structure of the MTSC ligand…
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Keywords:
new mononuclear;
geometry;
thiosemicarbazone;
metal complexes ... See more keywords