Facile Os-Os bond cleavage in the reactions of [Os3(CO)10(NCMe)2] and [Os3(CO)10(μ-H)2] with tetramethylthiuram disulfide (tmtd): Syntheses and crystal structures of new polynuclear osmium carbonyl complexes containing a dimethyldithiocarbamate ligand(s)
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DOI: 10.1016/j.jorganchem.2020.121133
Abstract: Abstract The reaction of the labile triosmium cluster [Os3(CO)10(NCMe)2] with tetramethylthiuram disulfide [(Me2NCS2)2, tmtd] has been investigated at room temperature. Conducting the reaction under mild conditions has permitted the isolation of the three new polynuclear… read more here.
Keywords: osmium; tetramethylthiuram disulfide; os3 ncme; new polynuclear ... See more keywords