A new synthesis approach for the generation of single chain CP mixtures composed of a few major compounds.
Sign Up to like & getrecommendations! Published in 2021 at "Chemosphere"
DOI: 10.1016/j.chemosphere.2021.132372
Abstract: Chlorinated paraffins (CPs) are complex mixtures, which consist of thousands of individual compounds with no dominant representative. Consequently, knowledge on structure and environmental relevance of individual CP congeners is poor. Similarly to the synthesis of… read more here.
Keywords: new synthesis; simple mixtures; technical mixtures; generation ... See more keywords
A new synthesis of 4′-trifluoromethyl-2,2′:6′,2″-terpyridine
Sign Up to like & getrecommendations! Published in 2021 at "Mendeleev Communications"
DOI: 10.1016/j.mencom.2021.04.035
Abstract: Reflux of two isomeric 3-amino-4,4,4-trifluoro-1-(2-pyridyl)but-2-en-1-one and 3-amino-1,1,1-trifluoro-4-(2-pyridyl)-but-3-en-2-one in acetic acid affords 4′-trifluoromethyl-2,2′:6′,2″-terpyridine (37%) with 1.4% admixture of 6′-trifluoromethyl-2,2′:4′,2″-terpyridine. read more here.
Keywords: trifluoromethyl; synthesis trifluoromethyl; trifluoromethyl terpyridine; new synthesis ... See more keywords
A new synthesis of highly functionalized cyclohexenes via a vinylogous Ferrier-Petasis cyclization reaction
Sign Up to like & getrecommendations! Published in 2017 at "Tetrahedron"
DOI: 10.1016/j.tet.2017.10.055
Abstract: Abstract Research on the O→C rearrangement reaction shows that alkoxydienes undergo a smooth rearrangement in a vinylogous manner with a catalytic amount of titanium (IV) chloride, which leads to highly substituted cyclohexenes a particularly useful… read more here.
Keywords: new synthesis; functionalized cyclohexenes; reaction; synthesis highly ... See more keywords
A new synthesis approach of hierarchical MoS2 nanoflakes toward hydrogen evolution in both acidic and alkaline media.
Sign Up to like & getrecommendations! Published in 2022 at "Chemical communications"
DOI: 10.1039/d2cc04020d
Abstract: Herein, ultrathin MoS2 flakes were prepared using a synergistic liquid phase precipitation method by applying ultrasound and microwave simultaneously. At 10 mA cm2 of electric current density, the MoS2 electrocatalysts' passing points are 176 mV… read more here.
Keywords: acidic alkaline; synthesis approach; approach hierarchical; new synthesis ... See more keywords
A New Synthesis Strategy for Rhodanine and Its Derivatives
Sign Up to like & getrecommendations! Published in 2021 at "Synlett"
DOI: 10.1055/a-1485-5925
Abstract: Rhodanine and its derivatives have been known as privileged structures in pharmacological research because of their wide spectrum of biological activities, but the synthesis method of rhodanine skeleton is limited. In this paper, not only… read more here.
Keywords: new synthesis; synthesis strategy; rhodanine derivatives; rhodanine ... See more keywords
Vinylogous Blaise Reaction: Conceptually New Synthesis of Pyridin-2-ones
Sign Up to like & getrecommendations! Published in 2018 at "Synlett"
DOI: 10.1055/s-0037-1610171
Abstract: A conceptually new synthesis of pyridine rings by a [C4 + CN] assembly has been developed by applying a vinylogous version of the classic Blaise reaction. The zinc-mediated reaction of (het)aryl or alkyl nitriles with… read more here.
Keywords: new synthesis; blaise reaction; pyridin ones; reaction ... See more keywords
A New Synthesis of Gefitinib
Sign Up to like & getrecommendations! Published in 2018 at "Synlett"
DOI: 10.1055/s-0037-1610375
Abstract: A four-step synthesis of the FDA-approved anticancer agent gefitinib was developed starting from 2,4-dichloro-6,7-dimethoxyquinazoline. Reaction temperatures were highly practical (0–55 °C), and chromatographic purifications were avoided. The ionic liquid trimethylammonium heptachlorodialuminate was used to monodemethylate the… read more here.
Keywords: new synthesis; synthesis gefitinib; synthesis;
A new synthesis method for planar Rubik’s cube mechanism
Sign Up to like & getrecommendations! Published in 2022 at "Proceedings of the Institution of Mechanical Engineers, Part C: Journal of Mechanical Engineering Science"
DOI: 10.1177/09544062221085135
Abstract: Planar mechanism is a kind of important mechanism, which plays a key role in daily life and industrial life. This paper presents a new synthesis method for planar Rubik’s cube mechanism (PRCM). Firstly, the composition… read more here.
Keywords: new synthesis; synthesis; planar; mechanism ... See more keywords
New Synthesis Routes toward Improvement of Natural Filler/Synthetic Polymer Interfacial Crosslinking
Sign Up to like & getrecommendations! Published in 2022 at "Polymers"
DOI: 10.3390/polym14030629
Abstract: Among the critical issues dictating bio-composite performance is the interfacial bonding between the natural fibers and polymer matrix. In this regard, this article presents new synthesis routes comprising the treatment and functionalization of both date… read more here.
Keywords: dpp; polymer; synthesis routes; new synthesis ... See more keywords