An (NH4)2S2O8-promoted cross-coupling of thiols/diselenides and sulfoxides for the synthesis of unsymmetrical disulfides/selenosulfides.
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DOI: 10.1039/d2cc01344d
Abstract: An (NH4)2S2O8-promoted cross-coupling of thiols/diselenides and sulfoxides to construct unsymmetrical disulfides/selenosulfides is disclosed. Control experiments demonstrate that (NH4)2S2O8 acts as an acid and an oxidant, while both ionic and radical routes are involved in the… read more here.
Keywords: cross coupling; thiols diselenides; promoted cross; 2s2o8 promoted ... See more keywords
Metal-free synthesis of C2-quaternary indolinones by (NH4)2S2O8 mediated oxidative dearomatization of indoles
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DOI: 10.1039/d2ra04191j
Abstract: An efficient metal-free, (NH4)2S2O8 mediated oxidative dearomatization of indoles for the construction of C2-quaternary indolinones was disclosed. A series of C2-quaternary indolinones derivatives with good functional group tolerance were obtained in moderate to excellent yields.… read more here.
Keywords: metal free; oxidative dearomatization; nh4 2s2o8; dearomatization indoles ... See more keywords