NH4I/tert-Butyl Hydroperoxide-Promoted Oxidative C–N Cleavage of Tertiary Amines Leading to Nitroaromatic Compounds
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DOI: 10.3184/174751917x15022797727991
Abstract: A NH4I/tert-butyl hydroperoxide-promoted oxidation of tertiary N-aryl-N,N-dialkylamines in DMSO has been developed to access nitroaromatic compounds. This methodology involves sequential N-dealkylation reactions in one-pot and a radical pathway is proposed. read more here.
Keywords: hydroperoxide promoted; nh4i tert; nitroaromatic compounds; tert butyl ... See more keywords