Design of Chiral NHC‐Carboxylates as Potential Ligands for Pd‐Catalyzed Enantioselective C−H Activation
Sign Up to like & getrecommendations! Published in 2021 at "Helvetica Chimica Acta"
DOI: 10.1002/hlca.202100015
Abstract: Despite numerous efforts, the synthesis of scalemic carbo- and heterocycles through Pd0-catalyzed C(sp3)-H activation employing chiral ancillary ligands or chiral bases is still limited. Inspired by the recently reported outstanding performance of IBiox-type NHC ligands… read more here.
Keywords: activation; nhc carboxylates; design chiral; nhc ... See more keywords
Bi4O5I2/nitrogen-doped hierarchical carbon (NHC) composites with tremella-like structure for high photocatalytic performance.
Sign Up to like & getrecommendations! Published in 2019 at "Chemosphere"
DOI: 10.1016/j.chemosphere.2019.05.043
Abstract: BiOI is a visible photocatalyst towards organic pollutant. In this work, biomass waste (withered typha grass) was used to fabricate nitrogen-doped hierarchical carbon (NHC) by an one-step carbonization route. Then NHC provided a good carrier… read more here.
Keywords: nitrogen doped; nhc; bi4o5i2; hierarchical carbon ... See more keywords
Self-assembled monolayers of N-heterocyclic carbene on gold: Stability under ultrasonic circumstance and computational study
Sign Up to like & getrecommendations! Published in 2018 at "Colloids and Surfaces A: Physicochemical and Engineering Aspects"
DOI: 10.1016/j.colsurfa.2017.11.041
Abstract: Abstract Self-assembled monolayers (SAMs) of N-heterocyclic carbene (NHC) are built up on gold substrate. Electrochemical impedance spectroscopy (EIS) tests show that the NHC-based SAMs exhibit high stability under ultrasonic circumstance, over 90% of NHC molecules… read more here.
Keywords: nhc; assembled monolayers; ultrasonic circumstance; self assembled ... See more keywords
Mechanism studies of oxidation and hydrolysis of Cu(I)–NHC and Ag–NHC in solution under air
Sign Up to like & getrecommendations! Published in 2020 at "Journal of Organometallic Chemistry"
DOI: 10.1016/j.jorganchem.2019.121025
Abstract: Abstract The decomposition of copper(I)–NHC and silver-NHC complexes in solution under air was studied. The Cu(I)–NHCs were oxidized into urea derivatives and hydrolysed into imidazoliums or benzimidazoliums. The decomposition of Ag–NHC with a saturated backbone… read more here.
Keywords: solution air; decomposition; nhc nhc; nhc ... See more keywords
PEPPSI type Pd(II)NHC complexes bearing chloro-/fluorobenzyl group: Synthesis, characterization, crystal structures, α-glycosidase and acetylcholinesterase inhibitory properties
Sign Up to like & getrecommendations! Published in 2021 at "Polyhedron"
DOI: 10.1016/j.poly.2021.115060
Abstract: Abstract This work reported the synthesis of a new PEPPSI (Pyridine Enhanced Precatalyst Preparation, Stabilization and Initiation) type Pd(II)N-heterocyclic carbene (NHC) complexes bearing halo-benzyl (4-florobenzyl and 2-chloro-4-florobenzyl) group. These new complexes were synthesized from the… read more here.
Keywords: nhc complexes; complexes bearing; crystal structures; peppsi type ... See more keywords
Heptadentate, Octadentate, Or Even Nonadentate? Denticity in the Unexpected Formation of an All-Carbon Donor-Atom Ligand in RhIII(Cp*)(Anthracenyl-NHC) Complexes.
Sign Up to like & getrecommendations! Published in 2021 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.1c00711
Abstract: Investigations on incorporating an N-flanking anthracenyl moiety to [Rh(Cp*)(NHC)Cl2] complexes surprisingly led to the formation of an intramolecular C-C bond between the Cp* and anthracenyl moieties, with additional auxiliary interactions between the metal and the… read more here.
Keywords: nhc; anthracenyl; carbon donor; formation ... See more keywords
Expedient Syntheses of Neutral and Cationic Au(I)–NHC Complexes
Sign Up to like & getrecommendations! Published in 2017 at "Organometallics"
DOI: 10.1021/acs.organomet.7b00622
Abstract: The synthesis and isolation of gold(I) precatalysts often requires the generation of several isolable intermediates as well as numerous purification steps. New protocols for the expedient synthesis of neutral [Au(OH)(NHC)] and [Au(CH2COCH3)(NHC)] species from [AuCl(NHC)]… read more here.
Keywords: cationic nhc; nhc; nhc complexes; expedient syntheses ... See more keywords
Hydrogen Transfer Activation via Stabilization of Coordinatively Vacant Sites: Tuning Long-Range π-System Electronic Interaction between Ru(0) and NHC Pendants
Sign Up to like & getrecommendations! Published in 2019 at "Organometallics"
DOI: 10.1021/acs.organomet.8b00850
Abstract: The insertion of a pyridine substituent on the lateral chain of N-heterocyclic carbene ligands enhances the catalytic activity of [Ru(CO)2(cyclopentadienone)(NHC)] complexes, precursors of Shvo-type catalysts, toward the hydrogenation of 4-fluoroacetophenone in refluxing 2-propanol as hydrogen… read more here.
Keywords: hydrogen transfer; via stabilization; transfer activation; nhc ... See more keywords
Neutral Dinuclear Copper(I)-NHC Complexes: Synthesis and Application in the Hydrosilylation of Ketones
Sign Up to like & getrecommendations! Published in 2017 at "ACS Catalysis"
DOI: 10.1021/acscatal.6b02723
Abstract: The synthesis of a class of highly stable neutral dinuclear Cu(I)-NHC complexes using 1,2,4-triazole as a bridging ligand is described. Various NHCs were used to generate a library of [Cu(μ-trz)(NHC)]2 complexes. Interestingly, [Cu(μ-trz)(IPr)]2 was found… read more here.
Keywords: nhc; neutral dinuclear; hydrosilylation ketones; nhc complexes ... See more keywords
N-Alkylation and N-Methylation of Amines with Alcohols Catalyzed by Nitrile-Substituted NHC–Ir(III) and NHC–Ru(II) Complexes
Sign Up to like & getrecommendations! Published in 2023 at "ACS Omega"
DOI: 10.1021/acsomega.2c06341
Abstract: A series of nitrile-modified N-heterocyclic carbene (NHC) complexes of Ir(III) (2a–e) and Ru(II) (3a–d) have been prepared by transmetallation of [IrCp*Cl2]2 and [RuCl2(p-cymene)]2 forming an in situ NHC–Ag complex. The structures of all complexes were… read more here.
Keywords: methylation; nhc; nhc iii; nhc complexes ... See more keywords
Ag–NHC anchored on silica: an efficient ultra-low loading catalyst for regioselective 1,2,3-triazole synthesis
Sign Up to like & getrecommendations! Published in 2019 at "New Journal of Chemistry"
DOI: 10.1039/c9nj03892b
Abstract: A silica-supported silver complex, Ag–NHC@SiO2, was prepared by an anchoring coordination technique, which was successfully employed for the click reaction under mild reaction conditions. read more here.
Keywords: silica efficient; nhc; efficient ultra; ultra low ... See more keywords