An Efficient Synthetic Approach to trans‐(NHC)2Pd(R)Br Type Complexes and Their Use in Suzuki–Miyaura Cross‐Coupling Reactions
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DOI: 10.1002/ejic.201700017
Abstract: Mixed organo-halo palladium complexes of the type trans-(NHC)2Pd(R)Br were conveniently obtained from trans-(NHC)2PdBr2 type complexes by the ligand substitution reaction. In particular, the trans-[1-(1S)-menthyl-4-(R1)-1,2,4-triazol-5- ylidene]2Pd(R2)Br [R1 = Et, R2 = CH2Ph (3a1); R1 = Et,… read more here.
Keywords: type complexes; nhc 2pd; trans nhc; cross ... See more keywords