Lability of Ta-NHC adducts as a synthetic route towards heterobimetallic Ta/Rh complexes.
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DOI: 10.1039/d0dt00344a
Abstract: We report the synthesis and characterization of a series of original tantalum/rhodium heterobimetallic species assembled by a bifunctional alkoxy-N-heterocyclic carbene (NHC) ligand platform (noted L). The heterotrimetallic [Ta(CH2tBu)(CHtBu)(μ-L)Rh2(COD)2Cl2]n, 2, and heterobimetallic [Ta(μ-L)(CHtBu)(CH2tBu)2Rh(COD)Cl], 4, complexes are… read more here.
Keywords: heterobimetallic complexes; synthetic route; nhc adducts; ch2tbu ... See more keywords