Mechanistic Studies of Carbonyl Allylation Mediated by (NHC)CuH: Isoprene Insertion, Allylation, and β-Hydride Elimination.
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DOI: 10.1021/acs.inorgchem.2c03402
Abstract: The ability of Cu-H complexes to undergo selective insertion of unsaturated hydrocarbons under mild conditions has rendered them valuable, versatile catalysts. The direct formation of Cu allyl intermediates from unfunctionalized 1,3-dienes and transient Cu hydrides… read more here.
Keywords: carbonyl allylation; mechanistic studies; nhc cuh; allylation ... See more keywords