Acyldifluoromethylation Enabled by NHC-Photoredox Cocatalysis.
Sign Up to like & getrecommendations! Published in 2022 at "Organic letters"
DOI: 10.1021/acs.orglett.2c01375
Abstract: With the continued interest in the properties of the difluoromethyl (CF2H) group, small molecules with alkyl-CF2H motifs have gained increasing attention. However, concise and efficient synthetic protocols to achieve these structures are still urgently needed.… read more here.
Keywords: enabled nhc; photoredox cocatalysis; nhc photoredox; acyldifluoromethylation enabled ... See more keywords
Suzuki-type cross-coupling of alkyl trifluoroborates with acid fluoride enabled by NHC/photoredox dual catalysis
Sign Up to like & getrecommendations! Published in 2022 at "Chemical Science"
DOI: 10.1039/d1sc06102j
Abstract: The Suzuki–Miyaura cross-coupling of C(sp3)-hybridised boronic compounds still remains a challenging task, thereby hindering the broad application of alkyl boron substrates in carbon–carbon bond-forming reactions. Herein, we developed an NHC/photoredox dual catalytic cross-coupling of alkyl… read more here.
Keywords: coupling alkyl; cross coupling; suzuki; nhc photoredox ... See more keywords