Synthesis of Complexes with Protic NH,NR‐NHC Ligands by Oxidative Addition of N‐Alkyl‐2‐iodoimidazoles to [M(PPh3)4] (M = Pd, Pt) Complexes
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DOI: 10.1002/ejic.201700403
Abstract: The oxidative addition of N-methyl-2-iodoimidazole 1 or N-benzyl-2-iodoimidazole 2 to complexes [Pd(PPh3)4] or [Pt(PPh3)4] followed by the protonation of the unsubstituted imidazolato ring-nitrogen atom yielded complexes trans-[M(NH,NMe-NHC)(PPh3)2I] (M = Pd: trans-[3]PF6; M = Pt: trans-[4]PF6)… read more here.
Keywords: pph3; nhc pph3; trans pf6; protic nhc ... See more keywords
Novel cis-[PdCl2(NHC)(PPh3)] complex: synthesis, crystal structure, spectral investigations, DFT and NCI studies, prediction of biological activity
Sign Up to like & getrecommendations! Published in 2020 at "Journal of Coordination Chemistry"
DOI: 10.1080/00958972.2020.1732360
Abstract: Abstract This study contains the synthesis of a heteroleptic Pd(II) cis–[PdCl2(NHC)(PPh3)] complex containing an N-heterocyclic carbene (NHC) and a triphenylphosphine (PPh3) ligand. The complex was prepared from the related [PdCl2(NHC)(3–Clpy)] complex (PEPPSI), replacing the 3-chloropyridine… read more here.
Keywords: pph3; nhc pph3; pdcl2 nhc; analysis ... See more keywords