The synthesis of novel boronate esters and N-Heterocyclic carbene (NHC)-stabilized boronate esters: Spectroscopy, antimicrobial and antioxidant studies
Sign Up to like & getrecommendations! Published in 2020 at "Journal of Organometallic Chemistry"
DOI: 10.1016/j.jorganchem.2020.121268
Abstract: Abstract A new class of cheap, easily-synthesizable and modifiable boronate esters (B1–B3) and their corresponding N-Heterocyclic Carbene (NHC)-stabilized boronate esters (B4–B6) have been synthesized for the first time under toluene reflux using a Dean-Stark apparatus… read more here.
Keywords: carbene nhc; boronate esters; stabilized boronate; boronate ... See more keywords
NHC-stabilized 1-hydrosilaimine: synthesis, structure and reactivity.
Sign Up to like & getrecommendations! Published in 2017 at "Chemical communications"
DOI: 10.1039/c7cc03912c
Abstract: A facile, straightforward synthesis of N-heterocyclic carbene (NHC)-stabilized 1-hydrosilaimine starting from a silicon(iv)-precursor is reported. It has been employed for the addition of an O-H bond of water under ambient conditions without any additional catalyst. read more here.
Keywords: synthesis structure; hydrosilaimine synthesis; stabilized hydrosilaimine; nhc stabilized ... See more keywords
Reactivity of an NHC-stabilized pyramidal hydrosilylene with electrophilic boron sources.
Sign Up to like & getrecommendations! Published in 2019 at "Dalton transactions"
DOI: 10.1039/c9dt00608g
Abstract: Silylenes have become an indispensable tool for molecular bond activation. Their use for the construction of silicon-boron bonds is uncommon in comparison to the numerous studies on silylene-derived silicon-element bond formations. Herein we investigate the… read more here.
Keywords: reactivity nhc; reactivity; pyramidal hydrosilylene; stabilized pyramidal ... See more keywords
The final fate of NHC stabilized dicarbon
Sign Up to like & getrecommendations! Published in 2017 at "Pure and Applied Chemistry"
DOI: 10.1515/pac-2016-1126
Abstract: Abstract In this paper we report the outcome of the reduction of NHC stabilized acetylenic dications, [NHC-Cn-NHC]2+ for n=2 and 4. The target compounds were NHC stabilized di- and tetracarbon in the form of NHC-Cn-NHC.… read more here.
Keywords: fate nhc; chemistry; final fate; stabilized dicarbon ... See more keywords