Chiral {Ni6PW9} Cluster-Organic Framework: Synthesis, Structure, and Properties.
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DOI: 10.1021/acs.inorgchem.2c00575
Abstract: A chiral three-dimensional polyoxometalate cluster-organic framework (POMCOF) H3[(btc)Ni6(μ3-OH)3(H2O)5(B-α-PW9O34)]·17H2O (1, btc = 1,2,4-benzenetricarboxylate) has been made under hydrothermal conditions in the absence of amine or chiral starting reagents. 1 shows high stability in CH3CN/DMF (1:3), acidic,… read more here.
Keywords: organic framework; cluster organic; ni6pw9 cluster; chiral ni6pw9 ... See more keywords