Reactivity of the diphosphinodithio ligated nickel(0) complex toward alkyl halides and resultant nickel(i) and nickel(ii)-alkyl complexes.
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DOI: 10.1039/c8dt03188f
Abstract: Diphosphinodithio ligated complexes of nickel(0), nickel(i) and nickel(ii)-alkyl with a reactivity relevant to the C-C bond formation were described. Stoichiometric reactions of the nickel(0) complex, [(P2S2)Ni] ([1]0, P2S2 = (Ph2PC6H4CH2S)2(C2H4)), with alkyl halides (RX) such… read more here.
Keywords: alkyl; nickel complex; nickel alkyl; nickel nickel ... See more keywords