Nickel bis(dithiolene) complexes for electrocatalytic hydrogen evolution: A computational study
Sign Up to like & getrecommendations! Published in 2018 at "Journal of Organometallic Chemistry"
DOI: 10.1016/j.jorganchem.2018.03.007
Abstract: Abstract The substituent effect of dithiolene ligand on electrocatalytic activity of Ni bis(dithiolene) towards hydrogen evolution reaction (HER) are thoroughly explored with computational methods. A series of differently substituted dithiolene ligands are compared and evaluated.… read more here.
Keywords: nickel bis; hydrogen evolution; bis dithiolene; dithiolene ... See more keywords
Stability of nickel bis(dicarbollide) complexes
Sign Up to like & getrecommendations! Published in 2019 at "Mendeleev Communications"
DOI: 10.1016/j.mencom.2019.09.019
Abstract: Reactions of nickel( iv ) bis(dicarbollide) with 2,2′-bipyridine or 1,10-phenanthroline in ethanol result in destruction of the metallacarborane cage with formation of the parent and 3-ethoxy substituted nido-carboranes. read more here.
Keywords: stability nickel; nickel bis; bis dicarbollide; dicarbollide complexes ... See more keywords
Controlling P–C/C–H Bond Cleavage in Nickel Bis(diphosphine) Complexes: Reactivity Scope, Mechanism, and Computations
Sign Up to like & getrecommendations! Published in 2020 at "Organometallics"
DOI: 10.1021/acs.organomet.0c00388
Abstract: The synthesis of heteroleptic [Ni(P2N2)(diphosphine)][BF4]2 complexes and the cleavage of P–C and C–H bonds of the P2N2 ligand in those complexes are reported. The products are five-coordinate comp... read more here.
Keywords: cleavage nickel; nickel bis; cleavage; controlling bond ... See more keywords
Carbon Nanotube Formic Acid Sensors Using a Nickel Bis( ortho-diiminosemiquinonate) Selector.
Sign Up to like & getrecommendations! Published in 2018 at "ACS sensors"
DOI: 10.1021/acssensors.8b00026
Abstract: Formic acid is corrosive, and a sensitive and selective sensor could be useful in industrial, medical, and environmental settings. We present a chemiresistor for detection of formic acid composed of single-walled carbon nanotubes (CNTs) and… read more here.
Keywords: ortho diiminosemiquinonate; nickel bis; bis ortho; formic acid ... See more keywords
Ambipolar Nickel Dithiolene Complex Semiconductors: From One- to Two-Dimensional Electronic Structures Based upon Alkoxy Chain Lengths.
Sign Up to like & getrecommendations! Published in 2022 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.2c08015
Abstract: Air-stable single-component ambipolar organic semiconductors that conduct both holes and electrons are highly desired but have been rarely realized. Neutral nickel bis(dithiolene) complexes are promising candidates that fulfill the stringent electronic requirements of shallow HOMO… read more here.
Keywords: nickel bis; dithiolene; air; effective intermolecular ... See more keywords
Conducting chiral nickel(ii) bis(dithiolene) complexes: structural and electron transport modulation with the charge and the number of stereogenic centres
Sign Up to like & getrecommendations! Published in 2021 at "Journal of Materials Chemistry C"
DOI: 10.1039/d1tc00439e
Abstract: Nickel(II) bis(dithiolene) complexes can provide crystalline conducting materials either in their monoanionic or neutral forms. Here we show that the use of chiral dithiolene ligands with one or two stereogenic centres, together with variation of… read more here.
Keywords: nickel bis; dddt; bis dithiolene; stereogenic centres ... See more keywords