Transient Formation and Reactivity of a High-Valent Nickel(IV) Oxido Complex
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DOI: 10.1021/jacs.7b04158
Abstract: A reactive high-valent dinuclear nickel(IV) oxido bridged complex is reported that can be formed at room temperature by reaction of [(L)2Ni(II)2(μ-X)3]X (X = Cl or Br) with NaOCl in methanol or acetonitrile (where L =… read more here.
Keywords: oxido; nickel oxido; reactivity; high valent ... See more keywords