Enhanced Relative Stability of Metallabenzenes versus Metallocenes upon Ring Perfluorination: Nickel, Palladium, and Platinum Systems
Sign Up to like & getrecommendations! Published in 2017 at "European Journal of Inorganic Chemistry"
DOI: 10.1002/ejic.201700810
Abstract: Perfluorination of one η5-C5H5 ring in the MC10H10 system (M = Ni, Pd, Pt) to give an MC10H5F5 system greatly destabilizes structures containing a perfluorinated pentahapto η5-C5F5 ring. As a result, the metallapentafluorobenzene structures (η5-C5H5)(MC5F5)… read more here.
Keywords: perfluorination; energy; palladium platinum; nickel palladium ... See more keywords
On the topology of highly branched polyethylenes prepared by amine−imine nickel and palladium complexes: the effect of ortho‐aryl substituents
Sign Up to like & getrecommendations! Published in 2018 at "Polymer International"
DOI: 10.1002/pi.5593
Abstract: Series of nickel and palladium complexes bearing amine-imine ligands in various ortho-aryl and backbone positions were prepared and investigated in ethene polymerization. Ethene polymerization initiated by symmetrically ortho-substituted nickel and palladium amine-imine catalysts is controlled.… read more here.
Keywords: topology; ortho aryl; nickel palladium; amine imine ... See more keywords
Recent advancements in α-diimine-nickel and -palladium catalysts for ethylene polymerization
Sign Up to like & getrecommendations! Published in 2021 at "European Polymer Journal"
DOI: 10.1016/j.eurpolymj.2021.110783
Abstract: Abstract The fascination of the well-defined metal catalysts for olefin polymerization is their capability to control the properties of the polymer such as topology (linear to highly branched), range of molecular weights and molecular weight… read more here.
Keywords: palladium catalysts; polymerization; ethylene polymerization; nickel palladium ... See more keywords
Trimetallic platinum-nickel-palladium nanorods with abundant bumps as robust catalysts for methanol electrooxidation.
Sign Up to like & getrecommendations! Published in 2019 at "Journal of colloid and interface science"
DOI: 10.1016/j.jcis.2019.11.026
Abstract: The development of high-performance catalysts is of great importance in direct alcohol fuel cells. One dimensional nanorods catalysts are hopeful candidates as efficient alcohol electrocatalysis. However, it is desirable to precisely modulate the surface morphology… read more here.
Keywords: one dimensional; dimensional nanorods; trimetallic platinum; nickel palladium ... See more keywords
Nickel(II) and palladium(II) triphenylphosphine complexes incorporating tridentate Schiff base ligands: Synthesis, characterization and biocidal activities
Sign Up to like & getrecommendations! Published in 2017 at "Journal of Molecular Structure"
DOI: 10.1016/j.molstruc.2017.08.050
Abstract: Abstract Nickel(II) and palladium(II) triphenylphosphine complexes incorporating tridentate Schiff bases have been prepared and characterized by elemental analysis as well as by spectroscopic techniques (FTIR & NMR). The synthesized compounds were assessed to check their… read more here.
Keywords: complexes incorporating; triphenylphosphine complexes; palladium triphenylphosphine; nickel palladium ... See more keywords
New nickel, palladium and platinum complexes of hydantoin derivative: Synthesis, characterization, theoretical study and biological activity
Sign Up to like & getrecommendations! Published in 2020 at "Polyhedron"
DOI: 10.1016/j.poly.2020.114478
Abstract: Abstract New Ni(II), Pd(II) and Pt(II) complexes of 5-methyl-5-(4-nitrophenyle)-hydantoin (L) were synthesized, characterized and their biological activities were evaluated. The resulting spectroscopic and theoretical data offered strong evidences for coordination of hydantoin based ligand from… read more here.
Keywords: theoretical study; palladium platinum; nickel palladium; activity ... See more keywords
Experimental and Computational Studies of High-Valent Nickel and Palladium Complexes
Sign Up to like & getrecommendations! Published in 2017 at "Organometallics"
DOI: 10.1021/acs.organomet.7b00613
Abstract: This article describes a detailed comparison of the organometallic chemistry of high-valent nickel and palladium model complexes supported by tris(pyrazolyl)borate and cycloneophyl ligands. The accessibility of the MIII and MIV oxidation states with each metal… read more here.
Keywords: experimental computational; valent nickel; high valent; nickel palladium ... See more keywords
Tridentate diarylamido-based pincer complexes of nickel and palladium: sidearm effects in the polymerization of norbornene.
Sign Up to like & getrecommendations! Published in 2019 at "Dalton transactions"
DOI: 10.1039/c9dt02361e
Abstract: Nickel and palladium complexes bearing new diarylamido-based unsymmetrical [NNNox] and [SNNox] pincer ligands were synthesized and tested for the polymerization of norbornene. Upon the activation of MAO, all the palladium complexes showed high catalytic activities… read more here.
Keywords: diarylamido based; polymerization; nickel palladium; sidearm effects ... See more keywords
Recent advances of dinuclear nickel- and palladium-complexes in homogeneous catalysis.
Sign Up to like & getrecommendations! Published in 2020 at "Chemical communications"
DOI: 10.1039/d0cc02542a
Abstract: The development of dinuclear transition metal catalysis has gained considerable momentum in recent years. The synergistic interaction between two metals enables the development of dinuclear metal catalysts with high efficiency, robustness and uniqueness. In this… read more here.
Keywords: dinuclear nickel; palladium complexes; catalysis; advances dinuclear ... See more keywords
A remote nonconjugated electron effect in insertion polymerization with α-diimine nickel and palladium species
Sign Up to like & getrecommendations! Published in 2020 at "Polymer Chemistry"
DOI: 10.1039/d0py00218f
Abstract: Systematic investigations of ligand electronic effects in late transition metal catalyzed ethylene polymerization and copolymerization have been widely explored in different catalytic systems. Generally, the electronic effect regulation in olefin polymerization can be achieved by… read more here.
Keywords: polymerization; effect; remote nonconjugated; nickel palladium ... See more keywords
Nickel–palladium bimetallic nanoparticles supported on multi-walled carbon nanotubes; versatile catalyst for Sonogashira cross-coupling reactions
Sign Up to like & getrecommendations! Published in 2023 at "RSC Advances"
DOI: 10.1039/d3ra00027c
Abstract: We have developed an efficient method to generate highly active nickel–palladium bimetallic nanoparticles supported on multi-walled carbon nanotubes (Ni–Pd/MWCNTs) by dry mixing of the nickel and palladium salts utilizing the mechanical energy of a ball-mill.… read more here.
Keywords: cross coupling; catalyst; sonogashira; sonogashira cross ... See more keywords