Nickel(ii) pincer complexes demonstrate that the remote substituent controls catalytic carbon dioxide reduction.
Sign Up to like & getrecommendations! Published in 2018 at "Chemical communications"
DOI: 10.1039/c7cc09507d
Abstract: The first example of a CNC pincer ligand with a central pyridinol ligand is reported in a nickel(ii) complex. This metal complex can be protonated or deprotonated reversibly in situ to switch on or off… read more here.
Keywords: pincer; reduction; nickel pincer; complexes demonstrate ... See more keywords
Highly economical and direct amination of sp3 carbon using low-cost nickel pincer catalyst
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DOI: 10.1039/d0ra09639c
Abstract: Developing more efficient routes to achieve C–N bond coupling is of great importance to industries ranging from products in pharmaceuticals and fertilizers to biomedical technologies and next-generation electroactive materials. Over the past decade, improvements in… read more here.
Keywords: catalyst; sp3; nickel pincer; pincer catalyst ... See more keywords
Unveiling the mechanisms and biosynthesis of a novel nickel-pincer enzyme.
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DOI: 10.1042/bst20220490
Abstract: The nickel-pincer nucleotide (NPN) coenzyme, a substituted pyridinium mononucleotide that tri-coordinates nickel, was first identified covalently attached to a lysine residue in the LarA protein of lactate racemase. Starting from nicotinic acid adenine dinucleotide, LarB… read more here.
Keywords: biosynthesis novel; unveiling mechanisms; mechanisms biosynthesis; nickel pincer ... See more keywords