Nickel(iii)-mediated oxidative cascades from a thiol-bearing nickel(ii) precursor to the nickel(iv) product.
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DOI: 10.1039/c7dt04137c
Abstract: A nickel(ii) complex, Ni(HPS2)2 (1) that contains two pendant thiols, is rapidly aerobically oxidized in the presence of an amine to produce a diamagnetic nickel(iv) complex, Ni(PS2)2 (2). This process was investigated spectroscopically at a… read more here.
Keywords: nickel iii; nickel; nickel precursor; iii mediated ... See more keywords