Four- and five-coordinate nickel(ii) complexes bearing new diphosphine–phosphonite and triphosphine–phosphite ligands: catalysts for N-alkylation of amines
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DOI: 10.1039/d1ra08961g
Abstract: The reaction of Ph2PCH2OH with PhPCl2 and PCl3 in the presence of Et3N afforded new phosphonite compounds PhP(OCH2PPh2)21 and P(OCH2PPh2)32, respectively. The reaction between 1 and [NiCl2(DME)] in dichloromethane gave the five-coordinate complex [NiCl2(1-κ3P,P,P)] 3.… read more here.
Keywords: presence; coordinate; nicl2 dme; complexes bearing ... See more keywords