Reversible Small‐Molecule Interactions with Coordinatively Unsaturated Metal Centers Held in Metallathiaborane Clusters
Sign Up to like & getrecommendations! Published in 2017 at "European Journal of Inorganic Chemistry"
DOI: 10.1002/ejic.201700539
Abstract: [8,8-(dppe)-nido-8,7-NiSB9H11] 1, [7-Et-8,8-(dppe)-nido-8,7-NiSB9H10] 2, [9-Et-8,8-(dppe)-nido-8,7-NiSB9H10] 3, and [2,2-(dppe)-closo-2,1-NiSB8H8] 4, are isolated from the reaction between Cs[arachno-SB9H12], Li[BHEt3] and [NiCl2(dppe)] at low temperature in yields of 30%, 1%, 0.1% and < 1%, respectively. The arachno-nickellathiadecaborane [6,6-(dppe)-arachno-6,9-NiSB8H10]… read more here.
Keywords: molecule; dppe; nido; metal ... See more keywords
Modified synthesis of Ru–Rh heterobimetallic metallacarboranes based on ruthenium exo-nido complexes and not accompanied by exo-nido → closo rearrangement
Sign Up to like & getrecommendations! Published in 2019 at "Mendeleev Communications"
DOI: 10.1016/j.mencom.2019.01.023
Abstract: The use of improved protocol for the reaction of rhodium acetylacetonate complexes (diene)RhAcac [diene is 1,5-cyclooctadiene or norbornadiene] with exo-nido-ruthenacarboranes 5,6,10-[RuCl(PPh3)2]-5,6,10-(μ-H)3-10-H-7,8-R2-7,8-C2B8H6 (R = H or Me) allowed us to synthesize three new binuclear complexes, wherein… read more here.
Keywords: nido; exo nido; synthesis heterobimetallic; ruthenium ... See more keywords
Pd-Catalyzed Selective B(6)-H Phosphorization of nido-Carboranes via Cascade Deboronation/B-H Activation from closo-Carboranes.
Sign Up to like & getrecommendations! Published in 2022 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.2c00993
Abstract: Efficient Pd-catalyzed regioselective B(6)-H phosphorization of nido-carboranes via cascade deboronation/B-H activation of readily available C-substituted o-carboranes with various phosphines using 3-methylpyridine or isoquinoline as a directing group in combination with pyridine ligands has been developed,… read more here.
Keywords: cascade deboronation; phosphorization nido; nido; carboranes via ... See more keywords
Synthesis and Structure of Nido-Carboranyl Azide and Its “Click” Reactions
Sign Up to like & getrecommendations! Published in 2021 at "Molecules"
DOI: 10.3390/molecules26030530
Abstract: Novel zwitter-ionic nido-carboranyl azide 9-N3(CH2)3Me2N-nido-7,8-C2B9H11 was prepared by the reaction of 9-Cl(CH2)3Me2N-nido-7,8-C2B9H11 with NaN3. The solid-state molecular structure of nido-carboranyl azide was determined by single-crystal X-ray diffraction. 9-N3(CH2)3Me2N-nido-7,8-C2B9H11 was used for the copper(I)-catalyzed azide-alkyne cycloaddition… read more here.
Keywords: 3me2n nido; ch2 3me2n; nido; nido carboranyl ... See more keywords
Synthesis of Zwitter-Ionic Conjugate of Nido-Carborane with Cholesterol
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DOI: 10.3390/molecules26216687
Abstract: 9-HC≡CCH2Me2N-nido-7,8-C2B9H11, a previously described carboranyl terminal alkyne, was used for the copper(I)-catalyzed azide-alkyne cycloaddition with azido-3β-cholesterol to form a novel zwitter-ionic conjugate of nido-carborane with cholesterol, bearing a 1,2,3-triazol fragment. The conjugate of nido-carborane with… read more here.
Keywords: nido carborane; conjugate nido; carborane cholesterol; nido ... See more keywords
Chemistry of CS2 and CS3 Bridged Decaborane Analogues: Regular Coordination Versus Cluster Expansion
Sign Up to like & getrecommendations! Published in 2023 at "Molecules"
DOI: 10.3390/molecules28030998
Abstract: In an effort to synthesize metallaheteroborane clusters of higher nuclearity, the reactivity of metallaheteroboranes, nido-[(Cp*M)2B6S2H4(CS3)] (Cp* = C5Me5) (1: M = Co; 2: M = Rh) with various metal carbonyls have been investigated. Photolysis of… read more here.
Keywords: chemistry; nido; cluster expansion; cs3 ... See more keywords