Synthesis of new nido-carborane based carboxylic acids and amines
Sign Up to like & getrecommendations! Published in 2018 at "Polyhedron"
DOI: 10.1016/j.poly.2018.07.009
Abstract: Abstract A series of new nido-carborane based carboxylic acids 10-HOOC(CH2)n(Me)S-7,8-C2B9H11 (n = 1–4) was prepared by alkylation of tetrabutylammonium salt of 10-methylthio-7,8-dicarba-nido-caborane with ω-halogenoalkyl esters or nitriles followed by acid hydrolysis. Likewise nido-carborane based amines 10-H2N(CH2)n(Me)S-7,8-C2B9H11 (n = 2,… read more here.
Keywords: carborane based; new nido; carboxylic acids; based carboxylic ... See more keywords
Closo- or Nido-Carborane Diphosphane as Responsible for Strong Thermochromism or Time Activated Delayed Fluorescence (TADF) in [Cu(N^N)(P^P)]0/.
Sign Up to like & getrecommendations! Published in 2021 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.1c03092
Abstract: Ortho-closo or ortho-nido-carborane-diphosphanes have been selected to prepare the heteroleptic cationic or neutral [Cu(N^N){(PPh2)2C2B10H10}]PF6 (1) and [Cu(N^N){(PPh2)2C2B9H10}] (2) [N^N = 2-(4-thiazolyl)benzimidazole], respectively. Complexes 1 and 2 display very different emissive behavior. Neutral complex 2 exhibits… read more here.
Keywords: time activated; delayed fluorescence; nido carborane; activated delayed ... See more keywords
Enhancing the thermally activated delayed fluorescence of nido-carborane-appended triarylboranes by steric modification of the phenylene linker
Sign Up to like & getrecommendations! Published in 2020 at "Inorganic chemistry frontiers"
DOI: 10.1039/d0qi00535e
Abstract: An approach to enhance the thermally activated delayed fluorescence (TADF) of nido-carborane-appended triarylboranes is proposed. A methyl group is introduced into the 4-position of the phenylene ring bearing the nido-carborane (7,8-dicarba-nido-undecaborane) cage, i.e., at the… read more here.
Keywords: delayed fluorescence; nido carborane; cage; thermally activated ... See more keywords
Preparation and cell imaging of a nido-carborane fluorescent complex based on multi-component polymerization
Sign Up to like & getrecommendations! Published in 2024 at "PLOS ONE"
DOI: 10.1371/journal.pone.0313661
Abstract: The biocompatibility of carborane was a difficult problem that had drawn a lot of study interest. Using multi-ion inlay binding, water-soluble polymers were created by encapsulating nido-carborane in diazaspirodecaniums such as para-poly-nido-carboanylazaspirodecanium [5,4] (p-PNC54), para-poly-nido-carboanylazaspirodecanium… read more here.
Keywords: carborane; nido carborane; nido carboanylazaspirodecanium; cell imaging ... See more keywords
Well Defined Rich Electronic Structure: Facile Approach for Nido-Carborane Fused Azaspirodecaniums in Water Solution
Sign Up to like & getrecommendations! Published in 2020 at "Journal of the Brazilian Chemical Society"
DOI: 10.21577/0103-5053.20190152
Abstract: A novel bis-dumbbell shape of a multi cation around a azaspirodecanium combined with nido-carborane was prepared in a single step in good yield starting from pyrrolidine and 1,3-dichloropropane to give one compound and from piperidine… read more here.
Keywords: well defined; structure; nido carborane; spectroscopy ... See more keywords
Polymeric nanomaterials encapsulating fluorescent polyindole-nido- carborane: design, synthesis and biological evaluation
Sign Up to like & getrecommendations! Published in 2024 at "Frontiers in Chemistry"
DOI: 10.3389/fchem.2024.1402640
Abstract: The water-soluble nido-carborane was prepared by alkali treatment of o-carborane. A polymer PInd containing a polyindole structure was synthesized and employed to label the modified o-carborane. Subsequently, four polymeric nanomaterials were synthesized with the objective… read more here.
Keywords: carborane; nido carborane; polymeric nanomaterials; nanomaterials encapsulating ... See more keywords
Synthesis of Zwitter-Ionic Conjugate of Nido-Carborane with Cholesterol
Sign Up to like & getrecommendations! Published in 2021 at "Molecules"
DOI: 10.3390/molecules26216687
Abstract: 9-HC≡CCH2Me2N-nido-7,8-C2B9H11, a previously described carboranyl terminal alkyne, was used for the copper(I)-catalyzed azide-alkyne cycloaddition with azido-3β-cholesterol to form a novel zwitter-ionic conjugate of nido-carborane with cholesterol, bearing a 1,2,3-triazol fragment. The conjugate of nido-carborane with… read more here.
Keywords: nido carborane; conjugate nido; carborane cholesterol; nido ... See more keywords
Synthesis of Novel Planar-Chiral Charge-Compensated nido-Carborane-Based Amino Acid
Sign Up to like & getrecommendations! Published in 2024 at "Molecules"
DOI: 10.3390/molecules29184487
Abstract: Amino acids with unusual types of chirality and their derivatives have recently attracted attention as precursors in the synthesis of chiral catalysts and peptide analogues with unique properties. In this study, we have synthesized a… read more here.
Keywords: carborane based; carborane; nido carborane; planar chiral ... See more keywords