Tuning of magnetic properties of the 2D CN-bridged NiII-NbIV framework by incorporation of guest cations of alkali and alkaline earth metals.
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DOI: 10.1039/d1dt00367d
Abstract: The reaction between [Ni(cyclam)]2+ (cyclam = 1,4,8,11-tetraazacyclotetradecane) and [Nb(CN)8]4- in concentrated water solutions of different s-block metal salts leads to the formation of 2-dimensional honeycomb-like coordination networks of the formula Mx[Ni(cyclam)]3[Nb(CN)8]2·nH2O (x = 2: M… read more here.
Keywords: bridged niii; tuning magnetic; magnetic properties; guest cations ... See more keywords