Catalytically Relevant Intermediates in the Ni-Catalyzed C(sp2)-H and C(sp3)-H Functionalization of Aminoquinoline Substrates.
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DOI: 10.1021/jacs.9b09109
Abstract: This Article describes the synthesis and characterization of cyclometalated aminoquinoline NiII σ-aryl and σ-alkyl complexes that have been proposed as key intermediates in Ni-catalyzed C-H functionalization reactions. These NiII complexes serve as competent catalysts for… read more here.
Keywords: catalytically relevant; niiii species; functionalization aminoquinoline; intermediates catalyzed ... See more keywords