Slow relaxation of the magnetization observed in mononuclear Ln-radical compounds with D4d geometry configurations.
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DOI: 10.1039/c8dt03809k
Abstract: The combination of LnIII ions (GdIII, TbIII or DyIII) and a pyrazole nitronyl nitroxide radical results in three isomorphous complexes, namely, [Ln(hfac)3(NIT-Pyz)]2 (Ln = Gd(1), Tb(2), Dy(3); hfac = hexafluoroacetylacetone; NIT-Pyz = 2-{3-pyrazolyl}-4,4,5,5-tetramethylimidazoline-1-oxyl-3-oxide). Single crystal… read more here.
Keywords: relaxation; relaxation magnetization; nit pyz; lniii ions ... See more keywords