Nitrene-mediated intermolecular N–N coupling for efficient synthesis of hydrazides
Sign Up to like & getrecommendations! Published in 2021 at "Nature Chemistry"
DOI: 10.1038/s41557-021-00650-0
Abstract: N–N linkages are found in many natural compounds and endow fascinating structural and functional properties. In comparison to the myriad methods for the construction of C–N bonds, chemistry for N–N coupling, especially in an intermolecular… read more here.
Keywords: nitrene mediated; synthesis hydrazides; chemistry; intermolecular coupling ... See more keywords
Efficient Buchwald–Hartwig and nitrene-mediated five-membered ring closure approaches to the total synthesis of quindoline. Unexpected direct conversion of a nitro group into a phosphazene
Sign Up to like & getrecommendations! Published in 2023 at "RSC Advances"
DOI: 10.1039/d3ra02468g
Abstract: Two total syntheses of quindoline, which take place through the intermediacy of 3-nitroquinoline derivatives, are reported. The general synthetic sequence involves construction of the latter by mechanochemical condensation of benzaldehydes with 2-amino-nitrostyrene, followed either by… read more here.
Keywords: quindoline unexpected; nitrene mediated; buchwald hartwig; nitro group ... See more keywords