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Published in 2023 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.2c12145
Abstract: Complexes featuring lanthanide-ligand multiple bonds are rare and highly reactive. They are important synthetic targets to understand 4f/5d-bonding in comparison to d-block and actinide congeners. Herein, the isolation and characterization of a bridging cerium(IV)-nitride complex:…
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Keywords:
cerium nitride;
nitride complex;
bridging cerium;
trinox ... See more keywords
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1
Published in 2022 at "Dalton transactions"
DOI: 10.1039/d1dt03952k
Abstract: A molybdenum-nitride complex bearing a pyridine-based PNP-type pincer ligand derived from dinitrogen is reacted with various kinds of carbon-centered electrophiles to functionalize the nitride ligand in the molybdenum complex. Methylation with MeOTf and acylation with…
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Keywords:
carbon;
nitride complex;
molybdenum;
pnp ... See more keywords