Synthesis and Characterization of a Bridging Cerium(IV) Nitride Complex.
Sign Up to like & getrecommendations! Published in 2023 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.2c12145
Abstract: Complexes featuring lanthanide-ligand multiple bonds are rare and highly reactive. They are important synthetic targets to understand 4f/5d-bonding in comparison to d-block and actinide congeners. Herein, the isolation and characterization of a bridging cerium(IV)-nitride complex:… read more here.
Keywords: cerium nitride; nitride complex; bridging cerium; trinox ... See more keywords
Synthesis and Catalytic Activity of Thorium Nitride Complex from Dinitrogen Reduction.
Sign Up to like & getrecommendations! Published in 2025 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.4c18519
Abstract: Metal nitride species are recognized as key intermediates in the conversion of dinitrogen (N2) to ammonia (NH3). In this work, we report the isolation of a multimetallic nitride-bridged thorium complex (2) by completely cleaving the… read more here.
Keywords: dinitrogen; thorium; nitride complex; catalytic activity ... See more keywords
Reactivity of molybdenum-nitride complex bearing pyridine-based PNP-type pincer ligand toward carbon-centered electrophiles.
Sign Up to like & getrecommendations! Published in 2022 at "Dalton transactions"
DOI: 10.1039/d1dt03952k
Abstract: A molybdenum-nitride complex bearing a pyridine-based PNP-type pincer ligand derived from dinitrogen is reacted with various kinds of carbon-centered electrophiles to functionalize the nitride ligand in the molybdenum complex. Methylation with MeOTf and acylation with… read more here.
Keywords: carbon; nitride complex; molybdenum; pnp ... See more keywords