Effect of acidity of oxide support on the activity and stability of μ-nitrido diiron phthalocyanine complex
Sign Up to like & getrecommendations! Published in 2019 at "Chemical Engineering Research and Design"
DOI: 10.1016/j.cherd.2019.02.023
Abstract: Abstract Various oxides, including Al2O3, Fe2O3, SiO2, and ZrO2, were employed as catalyst supports for the oxidation of cyclohexane by a μ-nitrido-bis[tetra(tert-butyl)phthalocyaninatoiron] complex. These oxide supports were characterized by Brunauer–Emmett–Teller surface area measurements and NH3… read more here.
Keywords: nitrido diiron; diiron phthalocyanine; activity; acidity ... See more keywords
Visible Light-Induced Oxidation of Alcohols by a Luminescent Osmium(VI) Nitrido Complex: Evidence for the Generation of PhIO+ as a Highly Active Oxidant in the Presence of PhIO.
Sign Up to like & getrecommendations! Published in 2023 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.3c00760
Abstract: Although alcohols are readily oxidized by a variety of oxidants, their oxidation by metal nitrido complexes is yet to be studied. We report herein visible-light-induced oxidation of primary and secondary alcohols to carbonyl compounds by… read more here.
Keywords: light induced; phio; nitrido; visible light ... See more keywords
Cleavage of an Aromatic C-C Bond in Ferrocene by Insertion of an Iridium Nitrido Nitrogen Atom.
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DOI: 10.1021/jacs.3c02781
Abstract: The intermolecular cleavage of C-C bonds is a rare event. Herein, we report on a late transition-metal terminal nitrido complex, which upon oxidation undergoes insertion of the nitrido nitrogen atom into the aromatic C-C bond… read more here.
Keywords: cleavage; bond ferrocene; aromatic bond; nitrido ... See more keywords
Photochemical nitrogenation of alkanes and arenes by a strongly luminescent osmium(VI) nitrido complex
Sign Up to like & getrecommendations! Published in 2019 at "Communications Chemistry"
DOI: 10.1038/s42004-019-0142-3
Abstract: The search for a highly active nitrido complex that can transfer its nitrogen atom to inert organic molecules remains a challenge to chemists. In this regard, the use of solar energy to generate a reactive… read more here.
Keywords: strongly luminescent; luminescent osmium; nitrogenation; osmium nitrido ... See more keywords